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Overview |
6 |
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Readers Guidance |
7 |
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Contents |
9 |
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1 Introduction |
14 |
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1.1 Objectives of This Work |
17 |
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1.1.1 Summary of Composites Considered |
18 |
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2 Classification of Composites |
19 |
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2.1 Volume Concentrations |
19 |
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2.2 Geometry at Fixed Phase Concentrations |
20 |
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2.2.1 Geometrical Classification |
21 |
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2.3 Composites with Variable Geometry |
22 |
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2.3.1 Geometrical Classification |
22 |
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2.3.2 Some Composite Examples |
26 |
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3 Preliminaries on Stress/Strain |
29 |
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3.1 Stiffness |
29 |
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3.1.1 Dilute Suspension |
31 |
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3.2 Stress |
32 |
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3.3 Composite Sti.ness Estimated by SCS |
32 |
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4 Composite Stress and Geometry |
35 |
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4.1 Volumetric Stress |
35 |
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4.1.1 CSA-Composites |
35 |
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4.1.2 Any Composite – Geometry Function |
36 |
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4.1.3 Geometry Function and Shape Function |
37 |
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4.1.4 Shape Functions – A Closer Look |
39 |
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4.1.5 Summary |
42 |
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4.2 Deviatoric Stress |
43 |
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4.2.1 Stress and Geometry |
43 |
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4.3 Summary on Stress and Geometry |
44 |
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4.3.1 Stress |
44 |
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4.3.2 Geo-Function |
44 |
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5 Composite Stiffness and Geometry |
46 |
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5.1 Bulk Modulus and Shear Modulus |
46 |
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5.1.1 Porous Materials and Stiff Pore Systems |
46 |
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5.2 Young’s Modulus and Poisson’s Ratio |
47 |
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5.3 Special Composites and Observations |
47 |
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5.3.1 CSA-Composites |
48 |
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5.3.2 Composites with Special Shear Moduli Geo-Independent Bulk Moduli |
48 |
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5.3.3 Paul/Hansen versus Geo-Functions |
49 |
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6 Composite Eigenstrain/Stress |
50 |
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6.1 Basics |
50 |
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6.1.1 Simple Composites |
51 |
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6.2 General Geometry |
51 |
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6.2.1 Eigenstrain and Eigenstress |
51 |
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6.2.2 Pore Pressure in Porous Materials |
52 |
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7 Quantification of Geometry |
53 |
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7.1 Shape Factors |
57 |
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7.1.1 DC-Composites |
57 |
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7.1.2 CD-Composites |
63 |
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7.1.3 MM-Composites |
64 |
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7.2 Shape Functions and Geo-Path |
67 |
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7.2.1 Default |
67 |
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7.2.2 Alternative I |
70 |
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7.2.3 Alternative II |
71 |
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7.3 Geo-Paths |
72 |
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8 Composite Theory – Elasticity |
74 |
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8.1 Illustrative Examples |
74 |
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8.1.1 DC-CD Composite |
74 |
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8.1.2 Crumbled Foils Composite |
76 |
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8.1.3 Particulate (DC-DC) Composite |
78 |
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8.2 Other Examples |
80 |
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8.2.1 Cracks |
80 |
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8.2.2 Special DC-CD Composites Isotropy |
84 |
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8.3 FEM-Analysis versus Theory |
87 |
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8.3.1 FEM-Analysis |
87 |
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8.3.2 Particulate Composite |
89 |
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8.3.3 Defective Particulate Composite |
91 |
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8.3.4 Pearls on a String Composite |
96 |
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8.3.5 Grid Composite |
100 |
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8.3.6 Cracked Material |
103 |
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8.3.7 Discussion of FEM-Analysis |
104 |
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8.4 Conclusion |
107 |
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9 Composite Theory – Conductivity |
108 |
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9.1 Theory |
108 |
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9.2 Illustrative Examples |
109 |
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9.2.1 Porous Materials and Stiff Pore Systems |
109 |
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9.2.2 Dilute Porous Materials and Stiff Pore Systems |
111 |
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9.2.3 Cracked Materials (Soft and Stiff Cracks) |
111 |
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9.2.4 Crumbled Foils Composite |
113 |
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9.3 Theory versus Experiments |
113 |
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9.3.1 Chloride Diffusion in HCP and HCP with Silica Fume |
113 |
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9.3.2 Thermal Conductivity of Plane-Isotropic Fiber Composite |
116 |
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9.4 Theory versus SCS-Estimates |
118 |
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9.5 Conclusion |
118 |
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10 Simplified Composite Theory – Elasticity |
121 |
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10.1 Basis of Analysis |
123 |
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10.1.1 Geometry |
123 |
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10.1.2 Quantification of Composite Geometry |
125 |
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10.1.3 Preparation of Composite Analysis |
129 |
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10.2 Analysis |
130 |
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10.2.1 Bounds and Other Accurate Stiffness Expressions |
131 |
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10.2.2 Test of Theory |
131 |
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10.3 Illustrative Examples |
133 |
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10.3.1 Composites with Spherical Particles (CSAP) |
134 |
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10.3.2 Nearly CSAP Composites |
134 |
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10.3.3 Phase Symmetric Composites |
135 |
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10.3.4 Eigenstrain/Stress versus Geometry |
140 |
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10.3.5 Porous Materials |
140 |
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10.4 Theory and Experiments |
145 |
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10.4.1 Some Irregular Geometries Non-Flexible Geometry – Interference |
145 |
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10.4.2 Various Porous Materials |
148 |
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10.4.3 Sulphur Impregnated Cement/Silicate System |
152 |
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10.4.4 Salt Infected Bricks |
154 |
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10.4.5 Non-Flexible Particles in Particulate Composite |
155 |
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10.4.6 Defective Phase Contact in Concrete |
157 |
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10.4.7 Hydrating Cement Paste and Concrete |
159 |
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10.5 Conclusion |
162 |
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11 Simplified Composite Theory – Conductivity |
163 |
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11.1 Illustrative Example |
163 |
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11.1.1 On the Accuracy of Simplification |
164 |
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11.2 Applications |
164 |
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11.2.1 Thermal Conductivity of Fire-Brick |
164 |
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11.2.2 Electrical Conductivity of Binary Metallic Mixtures |
164 |
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11.2.3 Chloride Di.usion in Cement Paste System |
166 |
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11.3 Conclusion |
169 |
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12 Diagnostic Aspects of Theory |
170 |
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12.1 Stiffness |
172 |
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12.1.1 Examination of Sti.ness Expressions Isotropy Check |
172 |
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12.2 Conductivity |
178 |
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12.2.1 Examination of SCS-Expressions Spheres: Böttcher/ Landauer |
178 |
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12.3 Discussion |
181 |
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13 Aspects of Materials Design |
184 |
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13.1 Geometries versus Properties |
184 |
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13.2 Design |
185 |
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13.3 Illustrative Examples |
185 |
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13.3.1 Stiffness |
185 |
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13.3.2 Conductivity |
187 |
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13.4 Discussion |
189 |
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14 Viscoelasticity |
190 |
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14.1 Stress-Strain Relations |
191 |
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14.1.1 Analogy Young’s Modulus |
192 |
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14.1.2 Vibrations |
194 |
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14.2 Models of Viscoelastic Materials |
196 |
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14.2.1 Simple Models |
197 |
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14.2.2 Less Simple Models |
197 |
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14.3 Summary, Analysis, and Approximate Analysis |
202 |
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14.3.1 Approximate Analysis |
203 |
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15 Viscoelastic Composites |
206 |
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15.1 Composite Analysis |
207 |
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15.1.1 Accurate Analysis |
207 |
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15.1.2 Approximate Analysis |
207 |
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15.2 Applications |
209 |
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15.2.1 Porous Materials and Stiff Pore Systems |
210 |
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15.2.2 Particulate Composite |
210 |
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15.2.3 Mature Cement Concrete |
211 |
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15.2.4 Young Concrete |
217 |
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15.2.5 In.uence of Geometry on Viscoelastic Composite Behavior Particulate Composite versus Grid Reinforced Composite |
217 |
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15.2.6 Monomer Impregnated HCP and Porous Glass |
222 |
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15.2.7 Damping of Wood |
225 |
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15.3 Discussion |
227 |
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16 Final Remarks |
228 |
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A Elasticity |
230 |
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A.1 Isotropy |
230 |
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A.1.1 Composite Aspects |
230 |
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A.1.2 Stress-Strain |
230 |
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A.2 Cubic Elasticity |
231 |
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A.2.1 Poly-Cubic Elasticity |
232 |
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A.2.2 Composite Aspects |
233 |
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B Dilute Particulate Composites |
234 |
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B.1 Cubic Stiffness, Shape Parameters, and Stress |
234 |
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B.1.1 Particle Stress |
235 |
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B.1.2 Isotropic Stiffness, Shape Coefficients, and Stress |
237 |
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B.1.3 Particle Stress |
237 |
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C SCS-Analysis |
238 |
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C.1 Stiffness |
238 |
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C.1.1 Spherical Particles |
239 |
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C.1.2 Various Particle Shapes and Cracks |
240 |
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C.1.3 Multi-Shaped Particles |
241 |
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C.2 Other Physical Properties |
242 |
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C.2.1 Spherical Particles |
243 |
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C.2.2 Particles of Various Shapes and Cracks |
243 |
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C.2.3 Multi-Shaped Particles |
245 |
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D General Viscoelastic Models |
246 |
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E HCP and Concrete |
248 |
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E.1 Volume Models |
248 |
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E.2 Porosity of Hardening Cement Paste |
249 |
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Notations |
251 |
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References |
254 |
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